Issue 7, 2010
From the journal:

Chemical Communications

Thermal reaction of a ruthenium bis(silyl) complex having a lutidine-based Si,N,Si ligand: formation of a μ-silyl(μ-silylene) diruthenium complex involving a 3c–2e Ru–Si–C interaction†

Takashi Komuroa  and  Hiromi Tobita*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
E-mail: tobita@m.tains.tohoku.ac.jp
Fax: +81 22 795 6543
Tel: +81 22 795 6539

Abstract

Thermal reaction of a bis(silyl) complex Ru{κ3Si,Si,N-2,6-(Me2SiCH2)2C5H3N}(CO)3 in refluxing toluene gave a dinuclear ruthenium complex Ru2(μ-SiMe2)[(Me2SiCH2)C5H3N{CH2Si(Me)CH2}C5H3N(CH2SiMe3)](CO)4, which has a 3c–2e Ru–Si–C interaction.

Graphical abstract: Thermal reaction of a ruthenium bis(silyl) complex having a lutidine-based Si,N,Si ligand: formation of a μ-silyl(μ-silylene) diruthenium complex involving a 3c–2e Ru–Si–C interaction

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Article information

DOI
https://doi.org/10.1039/B915395K
Article type
Communication
Submitted
29 Jul 2009
Accepted
07 Dec 2009
First published
08 Jan 2010

Chem. Commun., 2010,46, 1136-1137

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Thermal reaction of a ruthenium bis(silyl) complex having a lutidine-based Si,N,Si ligand: formation of a μ-silyl(μ-silylene) diruthenium complex involving a 3c–2e Ru–Si–C interaction

T. Komuro and H. Tobita, Chem. Commun., 2010, 46, 1136 DOI: 10.1039/B915395K

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