Issue 7, 2010
From the journal:

Chemical Communications

o-Carborane-assisted Lewis acidity enhancement of triarylboranes†

Jung Oh Huh,a   Hyungjun Kim,a   Kang Mun Lee,a   Yoon Sup Lee,a   Youngkyu Do*a  and  Min Hyung Lee*b  

* Corresponding authors

a Department of Chemistry, KAIST, Daejeon 305–701, Republic of Korea
E-mail: ykdo@kaist.ac.kr
Fax: +8242 869 2810
Tel: +8242 869 2829

b Department of Chemistry, University of Ulsan, Ulsan 680–749, Republic of Korea
E-mail: lmh74@ulsan.ac.kr
Fax: +8252 259 2348
Tel: +8252 259 2335

Abstract

The introduction of an o-carborane cage into the triarylborane significantly enhances the Lewis acidity of the boron atom leading to large increase in fluoride ion affinity.

Graphical abstract: o-Carborane-assisted Lewis acidity enhancement of triarylboranes

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Article information

DOI
https://doi.org/10.1039/B918263B
Article type
Communication
Submitted
07 Sep 2009
Accepted
20 Nov 2009
First published
15 Dec 2009

Chem. Commun., 2010,46, 1138-1140

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o-Carborane-assisted Lewis acidity enhancement of triarylboranes

J. O. Huh, H. Kim, K. M. Lee, Y. S. Lee, Y. Do and M. H. Lee, Chem. Commun., 2010, 46, 1138 DOI: 10.1039/B918263B

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