Issue 25, 2010
From the journal:

Chemical Communications

Trigonal bipyramidal magnetic molecules based on [MoIII(CN)6]3−†

Xin-Yi Wang,a   Matthew G. Hilfiger,a   Andrey Prosvirina  and  Kim R. Dunbar*a  

* Corresponding authors

a Department of Chemistry, Texas A&M University, College Station, Texas, USA
E-mail: dunbar@mail.chem.tamu.edu

Abstract

The trigonal bipyramidal molecules [M(tmphen)2]3[Mo(CN)6]2·(solvent) (M = Co, Ni; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) based on the [MoIII(CN)6]3− unit were prepared by loss of a cyanide ligand from [MoIII(CN)7]4− and found to exhibit ferromagnetic interactions between the MII and MoIII centers.

Graphical abstract: Trigonal bipyramidal magnetic molecules based on [MoIII(CN)6]3−

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Article information

DOI
https://doi.org/10.1039/C0CC00399A
Article type
Communication
Submitted
15 Mar 2010
Accepted
15 Apr 2010
First published
13 May 2010

Chem. Commun., 2010,46, 4484-4486

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Trigonal bipyramidal magnetic molecules based on [MoIII(CN)6]3−

X. Wang, M. G. Hilfiger, A. Prosvirin and K. R. Dunbar, Chem. Commun., 2010, 46, 4484 DOI: 10.1039/C0CC00399A

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