[FeIILSCoIIILS]2 ⇔ [FeIIILSCoIIHS]2 photoinduced conversion in a cyanide-bridged heterobimetallic molecular square

Julie Mercurol; Yanling Li; Emilio Pardo; Olivia Risset; Mannan Seuleiman; Hélène Rousselière; Rodrigue Lescouëzec; Miguel Julve

doi:10.1039/C0CC02024A

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[Fe^II_LSCo^III_LS]₂ ⇔ [Fe^III_LSCo^II_HS]₂ photoinduced conversion in a cyanide-bridged heterobimetallic molecular square†

Julie Mercurol,^a Yanling Li,^a Emilio Pardo,^a Olivia Risset,^a Mannan Seuleiman,^a Hélène Rousselière,^a Rodrigue Lescouëzec*^a and Miguel Julve^b

Author affiliations

* Corresponding authors

^a Institut Parisien de Chimie Moléculaire, Université Pierre et Marie Curie-Paris 6, UMR 7201, F-75252 Paris, France
E-mail: Rodrigue.lescouezec@upmc.fr
Fax: +33 144273841
Tel: +33 144275562

^b Departament de Química Inorgànica, Instituto de Ciencia Molecular (ICMOL), Universitat de València, 46980 Paterna, València, Spain

Abstract

The self-assembly of [Fe^III{B(pz)₄}(CN)₃]⁻ and [Co^II(bik)₂(S)₂]²⁺ affords the diamagnetic cyanide-bridged [Fe^II_LSCo^III_LS]₂ molecular square which is converted into the corresponding magnetic [Fe^III_LSCo^II_HS]₂ species under light irradiation at relatively low temperatures.

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Article information

DOI: https://doi.org/10.1039/C0CC02024A
Article type: Communication
Submitted: 22 Jun 2010
Accepted: 24 Sep 2010
First published: 22 Oct 2010

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Chem. Commun., 2010,46, 8995-8997

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[Fe^II_LSCo^III_LS]₂ ⇔ [Fe^III_LSCo^II_HS]₂ photoinduced conversion in a cyanide-bridged heterobimetallic molecular square

J. Mercurol, Y. Li, E. Pardo, O. Risset, M. Seuleiman, H. Rousselière, R. Lescouëzec and M. Julve, Chem. Commun., 2010, 46, 8995 DOI: 10.1039/C0CC02024A

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