Issue 42, 2010
From the journal:

Chemical Communications

FeIII/FeII regular charge order in metal–organic framework†

Manuela Eloísa Medina,a   Yves Dumont,b   Jean-Marc Grenèchec  and  Franck Millange*a  

* Corresponding authors

a Institut Lavoisier (UMR CNRS 8180), Université de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
E-mail: memedina@icmm.csic.es, franck.millange@uvsq.fr
Fax: 33 1 39 25 44 52
Tel: 33 1 39 25 43 30

b GEMaC (UMR CNRS 8635), Université de Versailles Saint-Quentin-en-Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France
E-mail: yves.dumont@uvsq.fr
Fax: 33 1 39 25 46 52
Tel: 33 1 39 25 46 91

c LPEC (UMR CNRS 6087), Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex, France
E-mail: jean-marc.greneche@univ-lemans.fr
Fax: 33 2 43 83 35 18
Tel: 33 2 43 83 33 01

Abstract

The hydrolysis of the DMF solvent (DMF = N,N′-dimethylformamide) generates in situ the template cations DMA+ (dimethylammonium cation): it leads to the first MOF type solid FeIII0.5FeII0.5(OH,F)(O2C–C6H4–CO2)·0.5DMA with a regular charge order FeIII/FeII and an anionic framework with pores filled by counter-cations which behaves as a quasi-1D AF system with alternate localized FeII and FeIII moments.

Graphical abstract: FeIII/FeII regular charge order in metal–organic framework

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Article information

DOI
https://doi.org/10.1039/C0CC02161J
Article type
Communication
Submitted
28 Jun 2010
Accepted
07 Sep 2010
First published
23 Sep 2010

Chem. Commun., 2010,46, 7987-7989

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FeIII/FeII regular charge order in metal–organic framework

M. E. Medina, Y. Dumont, J. Grenèche and F. Millange, Chem. Commun., 2010, 46, 7987 DOI: 10.1039/C0CC02161J

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