Hexacoordinate oxy-globin models Fe(Por)(NH3)(O2) react with NO to form only the nitrato analogs Fe(Por)(NH3)(η1-ONO2), even at ∼100 K†
Abstract
The oxy-globin models Fe(Por)(NH3)(O2), prepared by sequential reactions of O2 (18O2) and NH3 with thin porous layers of