Issue 43, 2010
From the journal:

Chemical Communications

Shape-persistent arylenevinylene macrocycles (AVMs) prepared viaacyclic dienemetathesis macrocyclization (ADMAC)†

Yinghua Jin,a   Aibo Zhang,ab   Yongshun Huanga  and  Wei Zhang*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Colorado, Boulder, USA
E-mail: wei.zhang@colorado.edu
Fax: (+1) 303-492-5894
Tel: (+1) 303-492-0652

b School of Natural and Applied Science, Northwestern Polytechnical University, Xian, P. R. China

Abstract

Shape-persistent arylenevinylene macrocycles (AVMs) were successfully prepared in one step from readily available aromatic diene monomers through olefin metathesis in good yields. 1H NMR, UV-Vis absorption and fluorescence studies revealed the aggregation behavior of the obtained macrocycles. SEM characterization showed AVM nanofibril formation.

Graphical abstract: Shape-persistent arylenevinylene macrocycles (AVMs) prepared via acyclic diene metathesis macrocyclization (ADMAC)

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Article information

DOI
https://doi.org/10.1039/C0CC02941F
Article type
Communication
Submitted
31 Jul 2010
Accepted
10 Sep 2010
First published
30 Sep 2010

Chem. Commun., 2010,46, 8258-8260

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Shape-persistent arylenevinylene macrocycles (AVMs) prepared via acyclic diene metathesis macrocyclization (ADMAC)

Y. Jin, A. Zhang, Y. Huang and W. Zhang, Chem. Commun., 2010, 46, 8258 DOI: 10.1039/C0CC02941F

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