Unusual transmetallation-induced formation of a C2-symmetric tetrapallada-macrocycle

Vincent T. Annibale; Liisa M. Lund; Datong Song

doi:10.1039/C0CC03314F

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Unusual transmetallation-induced formation of a C₂-symmetric tetrapallada-macrocycle†

Vincent T. Annibale,^a Liisa M. Lund^a and Datong Song*^a

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* Corresponding authors

^a Davenport Chemical Research Laboratories, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada
E-mail: dsong@chem.utoronto.ca
Fax: +1-416-978-7013
Tel: +1-416-978-7014

Abstract

We report the formation of a tetrapallada-macrocycle induced by an unusual transmetallation, in which an anionic bidentate chelate ligand is replaced by a phenyl ligand from phenylboronic acid, leaving the chloride ligands intact.

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Article information

DOI: https://doi.org/10.1039/C0CC03314F
Article type: Communication
Submitted: 17 Aug 2010
Accepted: 04 Sep 2010
First published: 28 Sep 2010

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Chem. Commun., 2010,46, 8261-8263

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Unusual transmetallation-induced formation of a C₂-symmetric tetrapallada-macrocycle

V. T. Annibale, L. M. Lund and D. Song, Chem. Commun., 2010, 46, 8261 DOI: 10.1039/C0CC03314F

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