Issue 1, 2011
From the journal:

Chemical Communications

Pyrene-fused subphthalocyanine†‡

Soji Shimizu,*a   Shota Nakano,a   Takahisa Hosoyaa  and  Nagao Kobayashi*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
E-mail: ssoji@m.tohoku.ac.jp, nagaok@m.tohoku.ac.jp
Fax: +81-22-795-7728
Tel: +81-22-795-7728

Abstract

A pyrene-fused subphthalocyanine synthesized from a reaction of 2,7-di-tert-butyl-4,5,9,10-tetracyanopyrene and tetrafluorophthalonitrile exhibits red-shifted Q-band absorption and a unique linear arrangement in the solid state caused by a π–π stacking interaction. The concave conjugation of the SubPc moiety and the planar conjugation of the pyrene moiety enhanced its co-crystallization with C60 molecules.

Graphical abstract: Pyrene-fused subphthalocyanine

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Article information

DOI
https://doi.org/10.1039/C0CC01877E
Article type
Communication
Submitted
14 Jun 2010
Accepted
04 Aug 2010
First published
23 Aug 2010

Chem. Commun., 2011,47, 316-318

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Pyrene-fused subphthalocyanine

S. Shimizu, S. Nakano, T. Hosoya and N. Kobayashi, Chem. Commun., 2011, 47, 316 DOI: 10.1039/C0CC01877E

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