Issue 1, 2011

Modifiable bidentate systems via N–C rearrangement in triazoles

Abstract

A new N–C rearrangement of substituted triazoles has been discovered. This process has been applied to the synthesis of diverse classes of mixed bidentate ligands and their metal complexes with highly modifiable backbones, including the first bisphosphine zwitterionic system based on a triazole frame.

Graphical abstract: Modifiable bidentate systems via N–C rearrangement in triazoles

Supplementary files

Article information

Article type
Communication
Submitted
23 Jun 2010
Accepted
04 Aug 2010
First published
23 Aug 2010

Chem. Commun., 2011,47, 319-321

Modifiable bidentate systems via N–C rearrangement in triazoles

E. A. S. Smith, G. Molev, M. Botoshansky and M. Gandelman, Chem. Commun., 2011, 47, 319 DOI: 10.1039/C0CC02033H

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