Issue 1, 2011
From the journal:

Chemical Communications

A new tetrathiafulvalene–phenoxynaphthacenequinone dyad: switching on the intramolecular electron-transfer with UV light irradiation and metal ion coordination†‡

Lina Jia,a   Guanxin Zhang,*a   Deqing Zhang,*a   Junfeng Xiang,a   Wei Xua  and  Daoben Zhua  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences, Organic Solids Laboratory, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: dqzhang@iccas.ac.cn

Abstract

The metal ion-promoted intramolecular electron transfer within TTF-based dyad 1 containing a photochromic PNQ unit can be switched on with UV light irradiation by taking advantage of the photochromic feature of the PNQ unit and the fact that the trans and ana forms of PNQ show different electron accepting capacity.

Graphical abstract: A new tetrathiafulvalene–phenoxynaphthacenequinone dyad: switching on the intramolecular electron-transfer with UV light irradiation and metal ion coordination

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Article information

DOI
https://doi.org/10.1039/C0CC02110E
Article type
Communication
Submitted
26 Jun 2010
Accepted
04 Aug 2010
First published
19 Aug 2010

Chem. Commun., 2011,47, 322-324

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A new tetrathiafulvalene–phenoxynaphthacenequinone dyad: switching on the intramolecular electron-transfer with UV light irradiation and metal ion coordination

L. Jia, G. Zhang, D. Zhang, J. Xiang, W. Xu and D. Zhu, Chem. Commun., 2011, 47, 322 DOI: 10.1039/C0CC02110E

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