A general route to synthesize supported isolated oxide and mixed-oxide nanoclusters at sizes below 5 nm

Abstract

A simple and efficient route to prepare supported nanocrystalline oxides is presented. The synthesis procedure, i.e. in situ autocombustion of a glycine complex, allows the production of nanocrystals in a porous matrix presenting larger pore size. An example of successful formation of 2–5 nm nanocrystals is given for a single oxide (Fe₂O₃), a mixed-oxide structure (LaCoO₃ perovskite-type) and a nickel-doped oxide.