Issue 9, 2011
From the journal:

Chemical Communications

A BODIPY-based fluorescent chemodosimeter for Cu(ii) driven by an oxidative dehydrogenation mechanism†

Dongping Wang,a   Yasuhiro Shiraishi*a  and  Takayuki Hiraia  

* Corresponding authors

a Research Center for Solar Energy Chemistry, and Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, Toyonaka 560-8531, Japan
E-mail: shiraish@cheng.es.osaka-u.ac.jp
Fax: +81 6 68506273
Tel: +81 6 68506271

Abstract

A boradiazaindacene (BODIPY) derivative containing a simple NO bidentate ligand shows a Cu2+-selective fluorescence in aqueous media. This is promoted via a coordination of Cu2+ followed by oxidative dehydrogenation of an amine moiety, leading to a formation of a fluorescent Cu+–Schiff base complex.

Graphical abstract: A BODIPY-based fluorescent chemodosimeter for Cu(ii) driven by an oxidative dehydrogenation mechanism

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC04069J
Article type
Communication
Submitted
25 Sep 2010
Accepted
20 Dec 2010
First published
13 Jan 2011

Chem. Commun., 2011,47, 2673-2675

Permissions

Request permissions

A BODIPY-based fluorescent chemodosimeter for Cu(II) driven by an oxidative dehydrogenation mechanism

D. Wang, Y. Shiraishi and T. Hirai, Chem. Commun., 2011, 47, 2673 DOI: 10.1039/C0CC04069J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements