Issue 9, 2011
From the journal:

Chemical Communications

X-Ray crystal structure of a heterobimetallic Al–Zn-oxide complex†

Stephan Schulz,*a   Jan Spielmann,a   Dieter Bläsera  and  Christoph Wölpera  

* Corresponding authors

a University of Duisburg-Essen, Universitätsstr. 5-7, S07 S03 C30, 45117 Essen, Germany
E-mail: stephan.schulz@uni-due.de
Fax: +49 201 1833830
Tel: +49 201 1834635

Abstract

OH/R (R = H, Me, i-Bu) exchange was observed in reactions of [MesnacnacZn(μ-OH)]2 (1) with metal complexes LnMR, whereas DippnacnacAl(Me)OH reacts with MesnacnacZnH with elimination of H2 and formation of the heterobimetallic Al–Zn-oxide complex MesnacnacZnOAl(Me)Dippnacnac 2.

Graphical abstract: X-Ray crystal structure of a heterobimetallic Al–Zn-oxide complex

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Article information

DOI
https://doi.org/10.1039/C0CC05599A
Article type
Communication
Submitted
15 Dec 2010
Accepted
12 Jan 2011
First published
31 Jan 2011

Chem. Commun., 2011,47, 2676-2678

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X-Ray crystal structure of a heterobimetallic Al–Zn-oxide complex

S. Schulz, J. Spielmann, D. Bläser and C. Wölper, Chem. Commun., 2011, 47, 2676 DOI: 10.1039/C0CC05599A

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