Issue 2, 2011
From the journal:

Chemical Communications

Cyclophosphates as ligands for cobalt(iii) in water†

Michael Montag,a   Christopher R. Clough,a   Peter Müllera  and  Christopher C. Cummins*a  

* Corresponding authors

a Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave, Room 6-435, Cambridge, USA
E-mail: ccummins@mit.edu
Fax: +1 617 253 7670
Tel: +1 617 253 5332

Abstract

Examination of cyclotriphosphate and cyclotetraphosphate as ligands for Co(III) in aqueous solutions revealed that cyclotetraphosphate affords stable complexes as a hemilabile ligand, while cyclotriphosphate exhibits facile hydrolysis.

Graphical abstract: Cyclophosphates as ligands for cobalt(iii) in water

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Article information

DOI
https://doi.org/10.1039/C0CC04342G
Article type
Communication
Submitted
11 Oct 2010
Accepted
05 Nov 2010
First published
29 Nov 2010

Chem. Commun., 2011,47, 662-664

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Cyclophosphates as ligands for cobalt(III) in water

M. Montag, C. R. Clough, P. Müller and C. C. Cummins, Chem. Commun., 2011, 47, 662 DOI: 10.1039/C0CC04342G

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