Issue 5, 2011
From the journal:

Chemical Communications

Enantioselective intramolecular Rauhut–Currier reaction catalyzed by chiral phosphinothiourea†

Jing-Jing Gong,a   Tian-Ze Li,a   Kun Pana  and  Xin-Yan Wu*ab  

* Corresponding authors

a Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai, P. R. China
E-mail: xinyanwu@ecust.edu.cn
Fax: +86 21 64252758
Tel: +86 21 64252011

b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P. R. China

Abstract

Chiral organophosphine-catalyzed enantioselective Rauhut–Currier reaction has been disclosed for the first time. With L-valine-derived phosphinothiourea, the intramolecular Rauhut–Currier reaction of bis(enones) was achieved in good yields (up to 99%) with excellent enantioselectivities (up to 99.4% ee).

Graphical abstract: Enantioselective intramolecular Rauhut–Currier reaction catalyzed by chiral phosphinothiourea

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Article information

DOI
https://doi.org/10.1039/C0CC04412A
Article type
Communication
Submitted
14 Oct 2010
Accepted
23 Nov 2010
First published
15 Dec 2010

Chem. Commun., 2011,47, 1491-1493

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Enantioselective intramolecular Rauhut–Currier reaction catalyzed by chiral phosphinothiourea

J. Gong, T. Li, K. Pan and X. Wu, Chem. Commun., 2011, 47, 1491 DOI: 10.1039/C0CC04412A

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