Issue 17, 2011

Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction

Abstract

A synthetic route to magnesium guanidinate compounds that avoids ligand redistribution is reported; selected derivatives are active pre-catalysts in the dimerization of aldehydes.

Graphical abstract: Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction

Supplementary files

Article information

Article type
Communication
Submitted
04 Nov 2010
Accepted
10 Mar 2011
First published
23 Mar 2011

Chem. Commun., 2011,47, 4995-4997

Bicyclic guanidinate compounds of magnesium and their activity as pre-catalysts in the Tishchenko reaction

B. M. Day, N. E. Mansfield, M. P. Coles and P. B. Hitchcock, Chem. Commun., 2011, 47, 4995 DOI: 10.1039/C0CC04789A

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