Issue 13, 2011
From the journal:

Chemical Communications

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes†

Romaeo Dallanegra,a   Alasdair P. M. Robertson,b   Adrian B. Chaplin,a   Ian Manners*b  and  Andrew S. Weller*a  

* Corresponding authors

a Department of Chemistry, Inorganic Chemistry Laboratories, University of Oxford, Oxford, UK, OX1 3QR
E-mail: andrew.weller@chem.ox.ac.uk

b School of Chemistry, University of Bristol, Cantocks Close, Bristol, UK, BS8 1TS
E-mail: Ian.Manners@bristol.ac.uk

Abstract

Efficient catalysts for the dehydrocoupling or dehydropolymerisation of H3B·NMexH(3−x) (x = 1, 2) have been developed by variation of the P–Rh–P angle in {Rh(Ph2P(CH2)nPPh2)}+ fragments (n = 2–5).

Graphical abstract: Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CC05460G
Article type
Communication
Submitted
08 Dec 2010
Accepted
20 Jan 2011
First published
03 Feb 2011

Chem. Commun., 2011,47, 3763-3765

Permissions

Request permissions

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

R. Dallanegra, A. P. M. Robertson, A. B. Chaplin, I. Manners and A. S. Weller, Chem. Commun., 2011, 47, 3763 DOI: 10.1039/C0CC05460G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements