Issue 13, 2011

A unique 2D → 3D polycatenation cobalt(ii)-based molecule magnet showing coexistence of paramagnetism and canted antiferromagnetism

Abstract

A novel entangled architecture [Co1.5(bpmp)(Hcda)(cda)(H2O)] (1) based on 44-sql subunits, showing an interesting 2D → 3D inclined polycatenation structure feature, is reported. Magnetic investigation shows that compound 1 exhibits coexistence of paramagnetism and canted antiferromagnetism with Tc of 48 K.

Graphical abstract: A unique 2D → 3D polycatenation cobalt(ii)-based molecule magnet showing coexistence of paramagnetism and canted antiferromagnetism

Supplementary files

Additions and corrections

Article information

Article type
Communication
Submitted
14 Dec 2010
Accepted
18 Feb 2011
First published
28 Feb 2011

Chem. Commun., 2011,47, 3766-3768

A unique 2D → 3D polycatenation cobalt(II)-based molecule magnet showing coexistence of paramagnetism and canted antiferromagnetism

B. Xu, X. Lin, Z. He, Z. Lin and R. Cao, Chem. Commun., 2011, 47, 3766 DOI: 10.1039/C0CC05567K

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