A unique 2D → 3D polycatenation cobalt(ii)-based molecule magnet showing coexistence of paramagnetism and canted antiferromagnetism†
Abstract
A novel entangled architecture [Co1.5(bpmp)(Hcda)(cda)(H2O)] (1) based on 44-sql subunits, showing an interesting 2D → 3D inclined polycatenation structure feature, is reported. Magnetic investigation shows that compound 1 exhibits coexistence of paramagnetism and canted antiferromagnetism with Tc of 48 K.