Issue 14, 2011
From the journal:

Chemical Communications

Functionalization of the corrole ring: the role of isocorrole intermediates†

Luca Tortora,a   Sara Nardis,a   Frank R. Fronczek,b   Kevin M. Smithb  and  Roberto Paolesse*a  

* Corresponding authors

a Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma “Tor Vergata”, via della Ricerca Scientifica 1, 00133 Rome, Italy
E-mail: paolesse@uniroma2.it
Fax: +39 06 72594328
Tel: +39 06 72594752

b Department of Chemistry, Louisiana State University, Baton Rouge, USA

Abstract

Bromination of 3-nitro-5,10,15-triarylcorrole selectively provides two regioisomers, depending on the reaction pathway. An isocorrole species is the key intermediate to drive the reaction towards the 2-Br-17-nitro regioisomer.

Graphical abstract: Functionalization of the corrole ring: the role of isocorrole intermediates

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Article information

DOI
https://doi.org/10.1039/C0CC05837H
Article type
Communication
Submitted
29 Dec 2010
Accepted
09 Feb 2011
First published
24 Feb 2011

Chem. Commun., 2011,47, 4243-4245

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Functionalization of the corrole ring: the role of isocorrole intermediates

L. Tortora, S. Nardis, F. R. Fronczek, K. M. Smith and R. Paolesse, Chem. Commun., 2011, 47, 4243 DOI: 10.1039/C0CC05837H

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