Issue 19, 2011
From the journal:

Chemical Communications

Direct electrochemical imidation of aliphatic aminesvia anodic oxidation†

Li Zhang,a   Ji-Hu Su,b   Sujing Wang,b   Changfeng Wan,a   Zhenggen Zha,*a   Jiangfeng Du*b  and  Zhiyong Wang*a  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, Joint Laboratory of Green Synthetic Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, P. R. China
E-mail: zwang3@ustc.edu.cn, zgzha@ustc.edu.cn
Fax: +86-551-3603185
Tel: +86-551-3603185

b Hefei National Laboratory for Physical Sciences at Microscale and Department of Modern Physics, University of Science and Technology of China, Hefei, P. R. China
E-mail: djf@ustc.edu.cn
Fax: +86-551-3600039
Tel: +86-551-3600039

Abstract

Direct electrochemical synthesis of sulfonylamidines from aliphatic amines and sulfonylazides was realized with good to excellent yields. Traditional tertiary amine substrates were broadened to secondary and primary amines. The reaction intermediates were observed and a reaction mechanism was proposed and discussed.

Graphical abstract: Direct electrochemical imidation of aliphatic amines via anodic oxidation

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Article information

DOI
https://doi.org/10.1039/C1CC10871A
Article type
Communication
Submitted
15 Feb 2011
Accepted
21 Mar 2011
First published
11 Apr 2011

Chem. Commun., 2011,47, 5488-5490

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Direct electrochemical imidation of aliphatic aminesvia anodic oxidation

L. Zhang, J. Su, S. Wang, C. Wan, Z. Zha, J. Du and Z. Wang, Chem. Commun., 2011, 47, 5488 DOI: 10.1039/C1CC10871A

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