Issue 29, 2011
From the journal:

Chemical Communications

Zinc–zinc bonded decamethyldizincocene Zn2(η5-C5Me5)2 as catalyst for the inter- and intramolecular hydroamination reaction†

Anja Lühl,a   Hari Pada Nayek,a   Siegfried Blechert*b  and  Peter W. Roesky*a  

* Corresponding authors

a Institut für Anorganische Chemie, Karlsruher Institut für Technologie (KIT), Engesserstr. 15, 76131 Karlsruhe, Germany
E-mail: roesky@kit.edu
Fax: (+49) 721-608-44854
Tel: (+49) 721-608-46117

b Technische Universität Berlin, Institut für Chemie, Straße des 17. Juni 135, 10623 Berlin, Germany
E-mail: blechert@chem.tu-berlin.de
Fax: +49 (0)30-31 42 36 19
Tel: +49 (0)30-31 42 23 55

Abstract

The Zn–Zn bonded compound [(η5-Cp*)2Zn2] was investigated as catalyst for the inter- and intramolecular hydroamination reaction. High reaction rates under mild conditions were observed. This is the first application of a Zn–Zn bonded compound as catalyst.

Graphical abstract: Zinc–zinc bonded decamethyldizincocene Zn2(η5-C5Me5)2 as catalyst for the inter- and intramolecular hydroamination reaction

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Article information

DOI
https://doi.org/10.1039/C1CC12461G
Article type
Communication
Submitted
27 Apr 2011
Accepted
05 Jun 2011
First published
24 Jun 2011

Chem. Commun., 2011,47, 8280-8282

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Zinc–zinc bonded decamethyldizincocene Zn2(η5-C5Me5)2 as catalyst for the inter- and intramolecular hydroamination reaction

A. Lühl, H. Pada Nayek, S. Blechert and P. W. Roesky, Chem. Commun., 2011, 47, 8280 DOI: 10.1039/C1CC12461G

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