Issue 37, 2011
From the journal:

Chemical Communications

Rhodium-catalyzed direct ortho C–H olefination of phenol derivatives†

Chao Fenga  and  Teck-Peng Loh*a  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637616
E-mail: teckpeng@ntu.edu.sg
Fax: +65 6515 8229
Tel: +65 6513 8475

Abstract

Cationic rhodium complex-catalyzed olefination of phenol derivatives for the direct introduction of an α,β-unsaturated ester appendage is described. In addition, deuterium labelling and kinetic isotope effect studies were performed to probe the reaction mechanism.

Graphical abstract: Rhodium-catalyzed direct ortho C–H olefination of phenol derivatives

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Article information

DOI
https://doi.org/10.1039/C1CC14108B
Article type
Communication
Submitted
08 Jul 2011
Accepted
03 Aug 2011
First published
18 Aug 2011

Chem. Commun., 2011,47, 10458-10460

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Rhodium-catalyzed direct ortho C–H olefination of phenol derivatives

C. Feng and T. Loh, Chem. Commun., 2011, 47, 10458 DOI: 10.1039/C1CC14108B

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