Issue 42, 2011
From the journal:

Chemical Communications

Direct arylation of unactivated aromatic C–H bonds catalyzed by a stable organic radical†

Guo-Ping Yong,*a   Wen-Long She,a   Yi-Man Zhanga  and  Ying-Zhou Lia  

* Corresponding authors

a Department of Chemistry, University of Science and Technology of China, Hefei 230026, China
E-mail: gpyong@ ustc.edu.cn
Fax: +86-551-3601592

Abstract

A stable zwitterionic radical can catalyze direct arylation of unactivated aromatic C–H bonds via a chain homolytic aromatic substitution mechanism in the presence of potassium tert-butoxide.

Graphical abstract: Direct arylation of unactivated aromatic C–H bonds catalyzed by a stable organic radical

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Article information

DOI
https://doi.org/10.1039/C1CC14420K
Article type
Communication
Submitted
21 Jul 2011
Accepted
21 Sep 2011
First published
28 Sep 2011

Chem. Commun., 2011,47, 11766-11768

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Direct arylation of unactivated aromatic C–H bonds catalyzed by a stable organic radical

G. Yong, W. She, Y. Zhang and Y. Li, Chem. Commun., 2011, 47, 11766 DOI: 10.1039/C1CC14420K

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