Issue 42, 2011
From the journal:

Chemical Communications

C–N Bond formation vialigand-induced nucleophilicity at a coordinated triamidoamine ligand†

Annalese F. Maddox,a   Karla A. Erickson,a   Joseph M. Tanskib  and  Rory Waterman*a  

* Corresponding authors

a Department of Chemistry, University of Vermont, Burlington, USA
E-mail: rory.waterman@uvm.edu
Fax: 01 (802) 6556-8705
Tel: 01 (802) 656-0278

b Department of Chemistry, Vassar College, Poughkeepsie, USA

Abstract

Reaction of (N3N)ZrX complexes (X = amido, Cl−, CH3−) with carbodiimide substrates results in insertion into an Zr–N bond of the triamidoamine ligand rather than the Zr–X bond as has been observed for related (N3N)ZrX complexes (X = PR2−, AsR2−).

Graphical abstract: C–N Bond formation via ligand-induced nucleophilicity at a coordinated triamidoamine ligand

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Article information

DOI
https://doi.org/10.1039/C1CC15179G
Article type
Communication
Submitted
19 Aug 2011
Accepted
12 Sep 2011
First published
28 Sep 2011

Chem. Commun., 2011,47, 11769-11771

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C–N Bond formation via ligand-induced nucleophilicity at a coordinated triamidoamine ligand

A. F. Maddox, K. A. Erickson, J. M. Tanski and R. Waterman, Chem. Commun., 2011, 47, 11769 DOI: 10.1039/C1CC15179G

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