Novel metal–organic frameworks (MOFs) based on heterometallic nodes and 5-methylisophthalate linkers†
Abstract
Based on 5-methylisophthalate organic linkers, two novel metal–organic frameworks (MOFs) have been assembled from Zn2Na(COO)6 and Zn5K(COO)12 secondary building units (SBUs), which contain 3D anionic frameworks with 1D nanotubular helical channels replete with hydrated