Issue 24, 2011
From the journal:

Dalton Transactions

A heterometallic sandwich complex of europium(ii) for luminescent studies†‡

Cheng-Ling Pan,*a   Yu-Song Pan,a   Jing Wanga  and  Jiang-Feng Song*b  

* Corresponding authors

a School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan, Anhui, China
E-mail: chengling_pan@126.com

b Department of Chemistry, College of Science, North University of China, Taiyuan, China
E-mail: jfsong0129@gmail.com

Abstract

A divalent europium complex [(LPh)2Eu{K(THF)2}2] (LPh = Ph2Si(NAr)2, Ar = 2,6-iPr2C6H3) (THF = Tetrahydrofuran) (2), which has a sandwich structure with potassium–arene π interactions, was synthesized in high yield via a one-pot process. This complex has been fully characterized, and luminescent studies showed that the 528 nm emission peak can be attributed to the 4f–5d transition of Eu2+.

Graphical abstract: A heterometallic sandwich complex of europium(ii) for luminescent studies

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Article information

DOI
https://doi.org/10.1039/C1DT10635J
Article type
Communication
Submitted
12 Apr 2011
Accepted
15 Apr 2011
First published
19 May 2011

Dalton Trans., 2011,40, 6361-6363

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A heterometallic sandwich complex of europium(II) for luminescent studies

C. Pan, Y. Pan, J. Wang and J. Song, Dalton Trans., 2011, 40, 6361 DOI: 10.1039/C1DT10635J

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