Issue 24, 2011
From the journal:

Dalton Transactions

First observation of light-induced spin change in vacuum deposited thin films of iron spin crossover complexes†

Holger Naggert,a   Alexander Bannwarth,a   Steffen Chemnitz,b   Thomas von Hofe,b   Eckhard Quandt*b  and  Felix Tuczek*a  

* Corresponding authors

a Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Max-Eyth-Str. 2, Kiel, Germany
E-mail: ftuczek@ac.uni-kiel.de

b Institut für Materialwissenschaft, Technische Fakultät der Christian-Albrechts-Universität Kiel, Kaiserstr. 2, Kiel, Germany
E-mail: eq@tf.uni-kiel.de

Abstract

Thin films of [Fe(H2Bpz)2(phen)] (1) and [Fe(H2Bpz)2(bipy)] (2) are prepared by vacuum deposition and investigated with respect to their spin crossover behaviour. For the first time light-induced excited spin state trapping (LIESST) is observed in such systems. T1/2 and TLIESST in the films are in agreement with the bulk values.

Graphical abstract: First observation of light-induced spin change in vacuum deposited thin films of iron spin crossover complexes

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Article information

DOI
https://doi.org/10.1039/C1DT10651A
Article type
Communication
Submitted
09 Feb 2011
Accepted
18 Apr 2011
First published
19 May 2011

Dalton Trans., 2011,40, 6364-6366

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First observation of light-induced spin change in vacuum deposited thin films of iron spin crossover complexes

H. Naggert, A. Bannwarth, S. Chemnitz, T. von Hofe, E. Quandt and F. Tuczek, Dalton Trans., 2011, 40, 6364 DOI: 10.1039/C1DT10651A

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