Issue 2, 2011

Intramolecular hydroalkoxylation in Brønsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine

Abstract

The SO3H-tethered imidazolium and triazolium salts, nonvolatile and recyclable Brønsted acidic ionic liquids, efficiently mediate intramolecular hydroalkoxylations of alkenyl alcohols. They have been successfully employed in the synthesis of (±)-centrolobine.

Graphical abstract: Intramolecular hydroalkoxylation in Brønsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine

Supplementary files

Article information

Article type
Communication
Submitted
10 Sep 2010
Accepted
25 Oct 2010
First published
15 Nov 2010

Org. Biomol. Chem., 2011,9, 374-378

Intramolecular hydroalkoxylation in Brønsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine

Y. Jeong, D. Kim, Y. Choi and J. Ryu, Org. Biomol. Chem., 2011, 9, 374 DOI: 10.1039/C0OB00701C

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