Normal and inverted redox potentials and structural changes tuned by medium effects in [M2Mo(η5-C5Me5)2(S2C6H4)2(CO)2] (M: Co, Rh)†
Abstract
Redox potential inversion was observed during the two-electron (2e−)
* Corresponding authors
a
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-Ku, Japan
E-mail:
nisihara@chem.s.u-tokyo.ac.jp
Fax: +81-3-5841-8063
Tel: +81-3-5841-4346
b Department of Materials Molecular Science, Institute for Molecular Science, 38 Nishigo-Naka, Myodaiji, Okazaki, Japan
c Department of Structural Molecular Science, The Graduate University for Advanced Studies, 38 Nishigo-Naka, Myodaiji, Okazaki, Japan
d Department of Physics, School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-Ku, Japan
e International Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Japan
f CREST, Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Japan
g Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, 4256, Nagatsuta, Midori-Ku, Japan
Redox potential inversion was observed during the two-electron (2e−)
S. Muratsugu, K. Sodeyama, F. Kitamura, S. Tsukada, M. Tada, S. Tsuneyuki and H. Nishihara, Chem. Sci., 2011, 2, 1960 DOI: 10.1039/C1SC00272D
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