Highly selective CO2 capture of an agw-type metal–organic framework with inserted amides: experimental and theoretical studies

Jingui Duan; Zhen Yang; Junfeng Bai; Baishu Zheng; Yizhi Li; Shuhua Li

doi:10.1039/C2CC16231H

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Highly selective CO₂ capture of an agw-type metal–organic framework with inserted amides: experimental and theoretical studies†

Jingui Duan,^a Zhen Yang,^b Junfeng Bai,*^a Baishu Zheng,^a Yizhi Li^a and Shuhua Li*^b

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* Corresponding authors

^a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P.R. China
E-mail: bjunfeng@nju.edu.cn

^b Institute of Theoretical and Computational Chemistry, Nanjing University, Nanjing 210093, P.R. China
E-mail: shuhua@nju.edu.cn

Abstract

An amide-inserted metal–organic framework (NJU-Bai3) presents high storage and high selectivity toward CO₂ and combines these two interesting characters which strongly support our expectation that amide groups can significantly enhance the CO₂ binding ability and selectivity of MOFs.

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Article information

DOI: https://doi.org/10.1039/C2CC16231H
Article type: Communication
Submitted: 07 Oct 2011
Accepted: 08 Dec 2011
First published: 12 Dec 2011

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Chem. Commun., 2012,48, 3058-3060

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Highly selective CO₂ capture of an agw-type metal–organic framework with inserted amides: experimental and theoretical studies

J. Duan, Z. Yang, J. Bai, B. Zheng, Y. Li and S. Li, Chem. Commun., 2012, 48, 3058 DOI: 10.1039/C2CC16231H

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Chemical Communications