Issue 25, 2012
From the journal:

Chemical Communications

A highly reduced cyanogenligand derived from cyanide reductive coupling†‡

Alexander R. Foxa  and  Christopher C. Cummins*a  

* Corresponding authors

a Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Room 6-435, Cambridge, MA 02139-4307, USA
E-mail: ccummins@mit.edu
Fax: +1 (617) 253-5332
Tel: +1 (617) 253-7670

Abstract

The synthesis, structure, and spectroscopic features of a bimetallic cyanogen complex obtained from the reductive coupling of cyanide by a niobium(IV) precursor are described, and a mechanism for the coupling reaction is proposed based on DFT calculations.

Graphical abstract: A highly reduced cyanogen ligand derived from cyanide reductive coupling

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Article information

DOI
https://doi.org/10.1039/C2CC17212G
Article type
Communication
Submitted
19 Nov 2011
Accepted
21 Jan 2012
First published
23 Jan 2012

Chem. Commun., 2012,48, 3061-3063

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A highly reduced cyanogen ligand derived from cyanide reductive coupling

A. R. Fox and C. C. Cummins, Chem. Commun., 2012, 48, 3061 DOI: 10.1039/C2CC17212G

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