Issue 25, 2012
From the journal:

Chemical Communications

Tuning the reactivity of Au-complexes in an Au(i)/chiral Brønsted acid cooperative catalytic system: an approach to optically active fused 1,2-dihydroisoquinolines†

Nitin T. Patil,*a   Anil Kumar Mutyala,a   Ashok Konalaa  and  Ramesh Babu Tellaa  

* Corresponding authors

a CPC Division, CSIR-Indian Institute of Chemical Technology, Hyderabad 500 607, India
E-mail: nitin@iict.res.in
Fax: +91-40-27193382

Abstract

An enantioselective cooperative catalysis protocol, utilizing achiral Au(I) complexes and chiral Brønsted acids, has been developed for the synthesis of optically pure fused 1,2-dihydroisoquinolines starting from 2-alkynylbenzaldehydes and 2-aminobenzamides.

Graphical abstract: Tuning the reactivity of Au-complexes in an Au(i)/chiral Brønsted acid cooperative catalytic system: an approach to optically active fused 1,2-dihydroisoquinolines

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Article information

DOI
https://doi.org/10.1039/C2CC17450B
Article type
Communication
Submitted
29 Nov 2011
Accepted
27 Jan 2012
First published
30 Jan 2012

Chem. Commun., 2012,48, 3094-3096

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Tuning the reactivity of Au-complexes in an Au(I)/chiral Brønsted acid cooperative catalytic system: an approach to optically active fused 1,2-dihydroisoquinolines

N. T. Patil, A. K. Mutyala, A. Konala and R. B. Tella, Chem. Commun., 2012, 48, 3094 DOI: 10.1039/C2CC17450B

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