Issue 47, 2012

Anti-Markovnikov additions to N-allylic derivatives involving ammonium–carbenium superelectrophiles

Abstract

Anti-Markovnikov additions to non-conjugated unsaturated amines in superacid are reported. In situ NMR studies, DFT calculations and labelled substrates reactions support the involvement of new ammonium–carbenium superelectrophiles in this original process.

Graphical abstract: Anti-Markovnikov additions to N-allylic derivatives involving ammonium–carbenium superelectrophiles

Supplementary files

Article information

Article type
Communication
Submitted
28 Mar 2012
Accepted
14 Apr 2012
First published
16 Apr 2012

Chem. Commun., 2012,48, 5877-5879

Anti-Markovnikov additions to N-allylic derivatives involving ammonium–carbenium superelectrophiles

G. Compain, A. Martin-Mingot, G. Frapper, C. Bachmann, M. Jouannetaud and S. Thibaudeau, Chem. Commun., 2012, 48, 5877 DOI: 10.1039/C2CC32246C

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