New cyclic aromatic carbene ligands bearing remote amino groups were developed. The oxidative addition of Pd(0) into the chloride precursors yielded the corresponding Pd(II) complexes whose carbene ligand was demonstrated to have stronger donor ability than classical NHCs.
S. Sugawara, S. Kojima and Y. Yamamoto, Chem. Commun., 2012, 48, 9735 DOI: 10.1039/C2CC33510G
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