Issue 70, 2012
From the journal:

Chemical Communications

Targeted synthesis of a porous borazine-linked covalent organic framework†

Karl T. Jackson,a   Thomas E. Reicha  and  Hani M. El-Kaderi*a  

* Corresponding authors

a Department of Chemistry, Virginia Commonwealth University, Richmond, USA
E-mail: helkaderi@vcu.edu
Fax: +1 804 828 8599
Tel: +1 804 828 7505

Abstract

The first microcrystalline borazine-linked polymer, BLP-2(H), has been synthesized. BLP-2(H) crystallizes into 2D sheets that stack in an eclipsed AA fashion, has high thermal stability (∼420 °C) and high porosity (SABET = 1178 m2 g−1) and it can store up to 2.4 wt% of hydrogen at 77 K and 15 bar with isosteric heat of adsorption of 6.8 kJ mol−1.

Graphical abstract: Targeted synthesis of a porous borazine-linked covalent organic framework

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2CC33583B
Article type
Communication
Submitted
18 May 2012
Accepted
12 Jul 2012
First published
16 Jul 2012

Chem. Commun., 2012,48, 8823-8825

Permissions

Request permissions

Targeted synthesis of a porous borazine-linked covalent organic framework

K. T. Jackson, T. E. Reich and H. M. El-Kaderi, Chem. Commun., 2012, 48, 8823 DOI: 10.1039/C2CC33583B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements