Issue 63, 2012
From the journal:

Chemical Communications

Kinetics of hydrogen abstraction by active metal hydroxo and oxo intermediates: revealing their unexpected similarities in the transition state†

Yujuan Wang,a   Song Shi,a   Huajun Wang,a   Dajian Zhua  and  Guochuan Yin*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
E-mail: gyin@hust.edu.cn
Fax: +86-27-87542632
Tel: +86-27-87543732

Abstract

The kinetics of hydrogen abstraction by manganese(IV) species having hydroxo or oxo group reveals that they have very similar reactive characters in the transition state of hydrogen abstraction.

Graphical abstract: Kinetics of hydrogen abstraction by active metal hydroxo and oxo intermediates: revealing their unexpected similarities in the transition state

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Article information

DOI
https://doi.org/10.1039/C2CC33615D
Article type
Communication
Submitted
19 May 2012
Accepted
19 Jun 2012
First published
02 Jul 2012

Chem. Commun., 2012,48, 7832-7834

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Kinetics of hydrogen abstraction by active metal hydroxo and oxo intermediates: revealing their unexpected similarities in the transition state

Y. Wang, S. Shi, H. Wang, D. Zhu and G. Yin, Chem. Commun., 2012, 48, 7832 DOI: 10.1039/C2CC33615D

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