Issue 63, 2012
From the journal:

Chemical Communications

A versatile polypeptoid platform based on N-allyl glycine†

Joshua W. Robinsona  and  Helmut Schlaad*a  

* Corresponding authors

a Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Research Campus Golm, 14424 Potsdam, Germany
E-mail: schlaad@mpikg.mpg.de
Fax: +49 331 5679502
Tel: +49 331 5679514

Abstract

N-Allyl glycine N-carboxyanhydride (NCA) was synthesized and polymerized by ring opening polymerization under homo- or heterophase conditions to afford well-defined polypeptoids (MW = 1.5–10.5 kg mol−1, PDI = 1.1–1.4). Poly(N-allyl glycine) demonstrated stimuli-responsive behaviour in water and was readily modified via thiol–ene photochemistry under experimentally benign conditions.

Graphical abstract: A versatile polypeptoid platform based on N-allyl glycine

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Article information

DOI
https://doi.org/10.1039/C2CC33881E
Article type
Communication
Submitted
30 May 2012
Accepted
18 Jun 2012
First published
02 Jul 2012

Chem. Commun., 2012,48, 7835-7837

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A versatile polypeptoid platform based on N-allyl glycine

J. W. Robinson and H. Schlaad, Chem. Commun., 2012, 48, 7835 DOI: 10.1039/C2CC33881E

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