Issue 80, 2012
From the journal:

Chemical Communications

First magnets based on thiocyanato-bridges†

Maliheh Mousavi,ab   Virginie Béreau,ab   Carine Duhayon,ab   Philippe Guionneauc  and  Jean-Pascal Sutter*ab  

* Corresponding authors

a CNRS, LCC (Laboratoire de Chimie de Coordination), 205, route de Narbonne, F-31077 Toulouse, France
E-mail: sutter@lcc-toulouse.fr

b Université de Toulouse, UPS, INPT, F-31077 Toulouse, France

c CNRS, Université de Bordeaux, ICMCB, 87 Av. Doc. A. Schweitzer, 33608 Pessac, France

Abstract

2-D NCS-bridged {3d–4d} molecule-based magnets, formed by reaction of [MoIII(NCS)6]3− with either NiII or CoII complexes, have been found to exhibit magnetic ordering with TC = 39 K for {Co3Mo2} while {Ni3Mo2} has a non-magnetic ground state as a result of exact compensation by the individual sub-lattices.

Graphical abstract: First magnets based on thiocyanato-bridges

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Article information

DOI
https://doi.org/10.1039/C2CC33877G
Article type
Communication
Submitted
30 May 2012
Accepted
22 Aug 2012
First published
04 Sep 2012

Chem. Commun., 2012,48, 10028-10030

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First magnets based on thiocyanato-bridges

M. Mousavi, V. Béreau, C. Duhayon, P. Guionneau and J. Sutter, Chem. Commun., 2012, 48, 10028 DOI: 10.1039/C2CC33877G

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