Issue 87, 2012
From the journal:

Chemical Communications

Structure–property relationship of homochiral and achiral supramolecular isomers obtained by one-pot synthesis†

Ling Qin,a   Jin-Song Hu,a   Ming-Dao Zhang,a   Zi-Jian Guoa  and  He-Gen Zheng*a  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P.R. China
E-mail: zhenghg@nju.edu.cn
Fax: +86-25-83314502

Abstract

Two supramolecular isomers, {[Co(L)(OBA)]·H2O}n (1), {[Co5O2(L)2(OBA)3]·7DMF}n (2), have been synthesized by one-pot reactions. Compound 1 has a homochiral architecture with low connectivity, and compound 2 is an achiral 3D framework with high 12-connectivity. It is unprecedent to get homochiral and achiral supramolecular isomers by one-pot synthesis.

Graphical abstract: Structure–property relationship of homochiral and achiral supramolecular isomers obtained by one-pot synthesis

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Article information

DOI
https://doi.org/10.1039/C2CC36003A
Article type
Communication
Submitted
18 Aug 2012
Accepted
11 Sep 2012
First published
12 Sep 2012

Chem. Commun., 2012,48, 10757-10759

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Structure–property relationship of homochiral and achiral supramolecular isomers obtained by one-pot synthesis

L. Qin, J. Hu, M. Zhang, Z. Guo and H. Zheng, Chem. Commun., 2012, 48, 10757 DOI: 10.1039/C2CC36003A

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