Issue 92, 2012
From the journal:

Chemical Communications

Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2†

Katsuhiko Takeuchia  and  Douglas W. Stephan*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario, Canada
E-mail: dstephan@chem.utoronto.ca

Abstract

The 1 : 1 mixture of tris(trimethylsilyl)phosphine and tris(2,3,5,6-tetrafluorophenyl)borane behaves as frustrated Lewis pair (FLP) and shows H2 and sequential two-step double CO2 activation with subsequent Me3Si group transfer.

Graphical abstract: Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2

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Article information

DOI
https://doi.org/10.1039/C2CC36470K
Article type
Communication
Submitted
05 Sep 2012
Accepted
09 Oct 2012
First published
09 Oct 2012

Chem. Commun., 2012,48, 11304-11306

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Silyl-migrations in frustrated Lewis pair chemistry: reactions of ((CH3)3Si)3P and B(C6F4H)3 with H2 and CO2

K. Takeuchi and D. W. Stephan, Chem. Commun., 2012, 48, 11304 DOI: 10.1039/C2CC36470K

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