Oxidative carbonylation of amines to formamides using NaIO4

Ciera J. Gerack; Lisa McElwee-White

doi:10.1039/C2CC36809A

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Oxidative carbonylation of amines to formamides using NaIO₄†

Ciera J. Gerack^a and Lisa McElwee-White*^a

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* Corresponding authors

^a Department of Chemistry and Center for Catalysis, University of Florida, Gainesville, USA
E-mail: lmwhite@chem.ufl.edu
Tel: +1 (0)352-392-8768

Abstract

Carbonylation of amines in methanol in the presence of NaIO₄ produces formamide derivatives in good to excellent yields without a transition metal catalyst.

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Article information

DOI: https://doi.org/10.1039/C2CC36809A
Article type: Communication
Submitted: 17 Apr 2012
Accepted: 08 Oct 2012
First published: 09 Oct 2012

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Chem. Commun., 2012,48, 11310-11312

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Oxidative carbonylation of amines to formamides using NaIO₄

C. J. Gerack and L. McElwee-White, Chem. Commun., 2012, 48, 11310 DOI: 10.1039/C2CC36809A

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