Issue 96, 2012
From the journal:

Chemical Communications

Iridium(iii) azuliporphyrins†

Timothy D. Lash,*a   Komal Pokharel,a   Matthias Zellerb  and  Gregory M. Ferrencea  

* Corresponding authors

a Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160, USA
E-mail: tdlash@ilstu
Fax: +1 (309) 438-5538
Tel: +1 (309) 438-8554

b Department of Chemistry, Youngstown State University, One University Plaza, Youngstown, USA

Abstract

Azuliporphyrins were reacted with [Ir(COD)Cl]2 in refluxing o- or p-xylene to give novel iridium(III) derivatives that regioselectively incorporated an oxidized solvent molecule. The iridium(III) is inserted within the porphyrinoid macrocycle and possesses an additional apical acyl unit.

Graphical abstract: Iridium(iii) azuliporphyrins

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Article information

DOI
https://doi.org/10.1039/C2CC37104A
Article type
Communication
Submitted
29 Sep 2012
Accepted
19 Oct 2012
First published
22 Oct 2012

Chem. Commun., 2012,48, 11793-11795

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Iridium(III) azuliporphyrins

T. D. Lash, K. Pokharel, M. Zeller and G. M. Ferrence, Chem. Commun., 2012, 48, 11793 DOI: 10.1039/C2CC37104A

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