Stepwise assembly of homochiral coordination polymers based on the precursor of an enantiopure Yb3Mn6 cluster

Yong Zheng; La-Sheng Long; Rong-Bin Huang; Lan-Sun Zheng

doi:10.1039/C2DT30667K

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Stepwise assembly of homochiral coordination polymers based on the precursor of an enantiopure Yb₃Mn₆ cluster†

Yong Zheng,^a La-Sheng Long,*^a Rong-Bin Huang^a and Lan-Sun Zheng^a

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* Corresponding authors

^a State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
E-mail: lslong@xmu.edu.cn
Fax: +86 592 218 3047

Abstract

Two homochiral coordination polymers, namely, [Yb^III₃Mn^III₆(L)₆(μ₂-OMe)₆(isonicotinate)₂(HOMe)₂][Yb^III₃Mn^III₆(L)₆(μ₂-OMe)₆(isonicotinate)₂(HOMe)₄](NO₃)₂·6MeOH·12H₂O (5) (H₃L = (S,E)-4-(2-hydroxybenzylideneamino)-2-hydroxybutanoic acid) and [Yb^III₃Mn^III₆Na(L)₆(μ₂-OMe)₆(OOCH)₃]I·17H₂O (6), have been constructed by utilizing a stable enantiopure [Yb^III₃Mn^III₆(L)₆(μ₂-OMe)₆]³⁺ (Yb₃Mn₆) cluster as a precursor.

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Article information

DOI: https://doi.org/10.1039/C2DT30667K
Article type: Communication
Submitted: 23 Mar 2012
Accepted: 16 Jul 2012
First published: 17 Jul 2012

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Dalton Trans., 2012,41, 10518-10520

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Stepwise assembly of homochiral coordination polymers based on the precursor of an enantiopure Yb₃Mn₆ cluster

Y. Zheng, L. Long, R. Huang and L. Zheng, Dalton Trans., 2012, 41, 10518 DOI: 10.1039/C2DT30667K

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