Unique in situ reduction of copper(II) forming an interesting photoluminescent stair-polymer of copper(I) with a Cu2S2 core

Subrata Jana; Prasanta Bhowmik; Shouvik Chattopadhyay

doi:10.1039/C2DT30871A

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Unique in situreduction of copper(ii) forming an interesting photoluminescent stair-polymer of copper(i) with a Cu₂S₂ core†

Subrata Jana,^a Prasanta Bhowmik^a and Shouvik Chattopadhyay*^a

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* Corresponding authors

^a Department of Chemistry, Inorganic Section, Jadavpur University, Kolkata – 700 032, India
E-mail: shouvik.chem@gmail.com
Tel: +91-33-2457-2941

Abstract

A novel thiocyanate bridged one-dimensional copper(I) polymer, [CuL(μ-1,1,3-SCN)]_n (L = 5,6-diphenyl-2,3-dihydropyrazine), has been synthesized and characterized by X-ray crystallography. The complex features a copper(I) stair-step polymeric coordination network with a Cu₂S₂ core. The complex shows strong fluorescence.

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Supplementary files

Crystal structure data TXT (14K)

Article information

DOI: https://doi.org/10.1039/C2DT30871A
Article type: Communication
Submitted: 21 Apr 2012
Accepted: 02 Jul 2012
First published: 03 Jul 2012

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Dalton Trans., 2012,41, 10145-10149

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Unique in situ reduction of copper(II) forming an interesting photoluminescent stair-polymer of copper(I) with a Cu₂S₂ core

S. Jana, P. Bhowmik and S. Chattopadhyay, Dalton Trans., 2012, 41, 10145 DOI: 10.1039/C2DT30871A

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Dalton Transactions