Issue 34, 2012
From the journal:

Dalton Transactions

Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire†

Thomas Cadenbach,a   Eva Hevia,a   Alan R. Kennedy,a   Robert E. Mulvey,*a   Janie-Anne Pickrella  and  Stuart D. Robertson*a  

* Corresponding authors

a WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow G1 1XL, Scotland, UK
E-mail: r.e.mulvey@strath.ac.uk, stuart.d.robertson@strath.ac.uk

Abstract

New coordination complexes of the neutral tripodal tetra-amine Me6TREN with tBu3Ga or tBu2Zn have been synthesised and studied with their molecular structures revealing, for the first time, coordination to metal centres via an η1 or η2 mode, adding to previously reported η3 and η4 ligated examples.

Graphical abstract: Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

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Article information

DOI
https://doi.org/10.1039/C2DT31061A
Article type
Communication
Submitted
16 May 2012
Accepted
20 Jun 2012
First published
22 Jun 2012

Dalton Trans., 2012,41, 10141-10144

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Accessing low denticity coordination modes of a high denticity tripodal ligand to complete its coordinative repertoire

T. Cadenbach, E. Hevia, A. R. Kennedy, R. E. Mulvey, J. Pickrell and S. D. Robertson, Dalton Trans., 2012, 41, 10141 DOI: 10.1039/C2DT31061A

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