Issue 48, 2012
From the journal:

Dalton Transactions

Trapping {BW12}2 tungstoborate: synthesis and crystal structure of hybrid [{(H2BW12O42)2O}{Mo6O6S6(OH)4(H2O)2}]14− anion†

V. S. Korenev,*abd   P. A. Abramov,ad   C. Vicent,c   D. A. Mainichev,a   S. Floquet,b   E. Cadot,*b   M. N. Sokolovad  and  V. P. Fedinad  

* Corresponding authors

a Nikolaev Institute of Inorganic Chemistry SB RAS, Prospect Lavrentyeva 3, 630090 Novosibirsk, Russia
E-mail: wkorenev@niic.nsc.ru
Fax: +7 383 330 9089
Tel: +7 383 316 5845

b Institut Lavoisier de Versailles, Université de Versailles Saint Quentin, UMR 8180, 45 avenue des Etats Unis, 78035 Versailles, France
E-mail: cadot@chimie.uvsq.fr
Fax: +33 01 39 25 44 52
Tel: +33 01 39 25 43 82

c Universitat Jaume I CIF: Q-6250003-H, Av. de Vicent Sos Baynat, s/n, 12071 Castelló de la Plana, Espanya
Fax: +34 964 72 90 16
Tel: +34 964 72 80 00

d Novosibirsk State Univeristy, Pirogova Str. 2, Novosibirsk, Russia

Abstract

Reaction between monolacunary {BW11} tungstoborate and oxothiocationic building block, {Mo2O2S2}, results in the formation of a new polyoxothiometalate with a unique architecture in which two [H2BW12O43]9− tungstoborate subunits are linked together with a hexamolybdate [MoV6O6S6(OH)4(H2O)2]2+ bridge.

Graphical abstract: Trapping {BW12}2 tungstoborate: synthesis and crystal structure of hybrid [{(H2BW12O42)2O}{Mo6O6S6(OH)4(H2O)2}]14− anion

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2DT31512B
Article type
Communication
Submitted
10 Jul 2012
Accepted
17 Aug 2012
First published
17 Aug 2012

Dalton Trans., 2012,41, 14484-14486

Permissions

Request permissions

Trapping {BW12}2 tungstoborate: synthesis and crystal structure of hybrid [{(H2BW12O42)2O}{Mo6O6S6(OH)4(H2O)2}]14− anion

V. S. Korenev, P. A. Abramov, C. Vicent, D. A. Mainichev, S. Floquet, E. Cadot, M. N. Sokolov and V. P. Fedin, Dalton Trans., 2012, 41, 14484 DOI: 10.1039/C2DT31512B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements