Issue 48, 2012
From the journal:

Dalton Transactions

Co-crystallisation of competing structural modes in geometrically constrained Jahn–Teller manganese(iii) complexes†‡

Caroline Murray,a   Brendan Gildea,a   Helge Müller-Bunz,a   Charles J. Hardingb  and  Grace G. Morgan*a  

* Corresponding authors

a School of Chemistry and Chemical Biology and the SFI-Strategic Research Cluster in Solar Energy Conversion, University College Dublin, Belfield, Dublin 4, Ireland
E-mail: grace.morgan@ucd.ie
Fax: (+353) 1-716-2127

b Department of Chemistry, The Open University, Walton Hall, Milton Keynes, UK

Abstract

The combination of Jahn–Teller distortion and chelating ligands produces a fine balance between competing coordination modes in manganese(III) resulting in well-ordered co-crystallization of two distinct assemblies from one set of components under a single set of conditions.

Graphical abstract: Co-crystallisation of competing structural modes in geometrically constrained Jahn–Teller manganese(iii) complexes

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Article information

DOI
https://doi.org/10.1039/C2DT31742G
Article type
Communication
Submitted
31 Jul 2012
Accepted
13 Sep 2012
First published
14 Sep 2012

Dalton Trans., 2012,41, 14487-14489

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Co-crystallisation of competing structural modes in geometrically constrained Jahn–Teller manganese(III) complexes

C. Murray, B. Gildea, H. Müller-Bunz, C. J. Harding and G. G. Morgan, Dalton Trans., 2012, 41, 14487 DOI: 10.1039/C2DT31742G

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