Issue 41, 2012
From the journal:

Dalton Transactions

Cationic complexes of silicon and germanium with (O,S)-chelate ligands†

Natalia A. Kalashnikova,a   Sergey Yu. Bylikin,*b   Aleksander A. Korlyukov,c   Aleksander G. Shipov,a   Yuri I. Baukov,a   Peter G. Taylorb  and  Alan R. Bassindalebd  

* Corresponding authors

a N. I. Pirogov Russian National Medical Research University, 1 Ostrovityanova St., Moscow, Russia
E-mail: baukov@rsmu.ru
Tel: (+7) 4954341100

b The Open University, Walton Hall, Milton Keynes, UK
E-mail: bylikin@chemlet.com
Tel: +44 (0)1908632182

c A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow, Russia
E-mail: alex@xrlab.ineos.ac.ru
Tel: (+7) 4991359214

d Key Lab Organosilicon Chem. & Mat. Tech., Ministry of Education, Hangzhou Normal University, Zhejiang, Hangzhou, China

Abstract

Synthesis and X-ray diffraction study of cationic bischelates MeSi(SCH2CONMe2)2+Cl− and MeGe(SCH2CONMe2)2+Br− are reported. According to X-ray data, the Si and Ge atoms in these compounds have distorted TBP environments with two coordinating oxygen atoms in axial positions.

Graphical abstract: Cationic complexes of silicon and germanium with (O,S)-chelate ligands

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Article information

DOI
https://doi.org/10.1039/C2DT31554H
Article type
Communication
Submitted
13 Jul 2012
Accepted
12 Sep 2012
First published
13 Sep 2012

Dalton Trans., 2012,41, 12681-12682

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Cationic complexes of silicon and germanium with (O,S)-chelate ligands

N. A. Kalashnikova, S. Yu. Bylikin, A. A. Korlyukov, A. G. Shipov, Y. I. Baukov, P. G. Taylor and A. R. Bassindale, Dalton Trans., 2012, 41, 12681 DOI: 10.1039/C2DT31554H

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