Issue 41, 2012
From the journal:

Dalton Transactions

Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes†

Suraj Soman,a   Gurmeet Singh Bindra,a   Avishek Paul,a   Robert Groarke,a   Jennifer C. Manton,a   Finn M. Connaughton,a   Martin Schulz,‡a   Danilo Dini,§a   Conor Long,a   Mary T. Prycea  and  Johannes G. Vos*a  

* Corresponding authors

a SRC for Solar Energy Conversion, School of Chemical Sciences, Dublin City University, Dublin 9, Dublin, Ireland
E-mail: han.vos@dcu.ie

Abstract

Novel cyclometallated iridium–Pt/Pd dinuclear complexes containing the bridging ligand 2,2′:5′,2′′-terpyridine (BPP) and the peripheral phenylpyridine (ppy) ligand produced hydrogen under both visible (470 nm) and UV (350 nm) irradiation. The turnover numbers using visible light were found to be significantly higher, indicating an interplay between two independent excited states, only one of which produces H2 efficiently.

Graphical abstract: Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C2DT32028B
Article type
Communication
Submitted
29 Aug 2012
Accepted
04 Sep 2012
First published
06 Sep 2012

Dalton Trans., 2012,41, 12678-12680

Permissions

Request permissions

Wavelength dependent photocatalytic H2 generation using iridium–Pt/Pd complexes

S. Soman, G. Singh Bindra, A. Paul, R. Groarke, J. C. Manton, F. M. Connaughton, M. Schulz, D. Dini, C. Long, M. T. Pryce and J. G. Vos, Dalton Trans., 2012, 41, 12678 DOI: 10.1039/C2DT32028B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements